Effect of Nanoparticles on the Thermal Stability and Reaction Kinetics in Ionic Nanofluids


Publication Highlights

  1. Through UV-Vis and FTIR spectroscopy, the nitrite concentration was monitored from room temperature to 500°C. Molten salt-based nanofluids between this temperature range show the more significant nitrites formation, up to 4% in front of pure sodium nitrate (up to 0.8%).
  2. The results indicate an influence in the chemical degradation due to the nature of the nanoparticles, the more alkaline NPs, the greater variation in absorbance for the temperature range.
  3. Nanoparticles helps to prevent humidity absorption, contributing to its higher chemical stability with lower hygroscopicity.
  4. Nanofluids exhibit higher thermal stability than pure NaNO3 despite the slight increase in nitrite concentration.

Funding Organizations

Spanish government: RTI2018-093849-B-C32, RTI2018-094757-BI00, MDM-2017-0767, MCIU/AEI/FEDER, UE).

Generalitat de Catalunya: DIOPMA (2017 SGR 188), CMSL (2017 SGR 13), Grant FI-DGR 2018 and Serra Húnter Associate Professorship.

Universitat de Barcelona: APIF-DGR 2018,  FI-DGR 2018.